nickel dimer

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: nickel dimer
• 英文别名: nickel cluster；nickel
• 化学式: Ni₂
• 分子量: 117.38
• InChiKey: XIKYYQJBTPYKSG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  nickel dimer 在 乙烯 作用下， 生成
  参考文献：
  名称：

  FTMS Studies of Sputtered Metal Cluster Ions: (II) The Chemistry of Nin+ with C2H4 and CH4 at Long Timescales

  摘要：

  AbstractNickel cluster cations, generated in an external source by sputtering with 20 keV Xe+ were transferred to the ICR cell of a Fourier transform mass spectrometer (FTMS), collisionally cooled, and trapped for long time periods. During storage, the chemistry of Nin+ was studied with ethylene and methane in the range n = 1 … 20. Rather than undergoing adsorption as an intact unit, C2H4 was dehydrogenated in the 1.2‐position to yield HCCH adducts Nin(C2H2)m+ with a dramatic size‐specificity: Whereas Nin+ ions proved absolutely inert for n = 1, 3, 4, they were found highly reactive from n = 5 on. Cyclotroning in the presence of C2H4 for up to 40 s, Ni5+ was found to add on a maximum of nine C2H2 ligands. A second “hidden” size‐specific effect was discovered between n = 11 and n = 12, where dehydrogenation intensifies to yield NinC6+ as final products. These are being discussed in terms of close‐packed lattice structures. Finally, the threshold for methane activation by Ni5+ leading to Ni5C+ was determined to be 2.0 ± 0.5 eV.

  DOI：

  10.1002/bbpc.19890931203
• 作为产物：
  描述：

  镍 以 gaseous matrix 为溶剂， 生成 nickel dimer 、 nickel
  参考文献：
  名称：

  Spectroscopic studies of nickel and iron clusters at 12 K

  摘要：

  The electronic and far-infrared spectra of nickel and iron clusters trapped in argon matrices at 12 K are reported. The ν3 antisymmetric stretching frequencies for Ni3 and Fe3 were observed for the first time at 198 and 180 cm−1, respectively. The fr and frr force constants for Ni3 are calculated to be 0.80 and 0.13 mdyn/Å, respectively. For Fe3 these are 0.67 and 0.13 mdyn/Å.

  DOI：

  10.1063/1.452699

文献信息

• Production of hydrated metal ions by fast ion or atom beam sputtering. Collision-induced dissociation and successive hydration energies of gaseous copper+ with 1-4 water molecules
  作者：Thomas F. Magnera、Donald E. David、Dusan Stulik、Robert G. Orth、Harry T. Jonkman、Josef Michl

  DOI：10.1021/ja00196a003

  日期：1989.7

  atoms or ions produces copious amounts of cluster ions, among which M+(H2O)n and/or M+OH(H2O)n frequently dominate. Variable-energy collision-induced dissociation of these ions in a triple quadrupole mass spectrometer yields the successive gas-phase solvation energies. Several known hydration and bond energies have been reproduced, and the first and second hydration energies of the Cu+ ion have been

  低温溅射金属盐、水合结晶过渡金属盐、磨砂金属表面和具有千电子伏能量稀有气体原子或离子的磨砂金属盐的冷冻水溶液，产生大量簇离子，其中 M+(H2O )n 和/或 M+OH(H2O)n 经常占主导地位。这些离子在三重四极杆质谱仪中的可变能量碰撞诱导解离产生连续的气相溶剂化能量。几个已知的水合能和键能已被重现，Cu+ 离子的第一和第二水合能分别确定为 35 ± 3 和 39 ± 3 kcal/mol。得出的结论是气态 Cu+ 更喜欢双配位。
• Park; Hauge; Margrave, High temperature science, 1988, vol. 25, # 1, p. 1 - 15
  作者：Park、Hauge、Margrave

  DOI：——

  日期：——
• Spectroscopy and electronic structure of jet‐cooled NiCu
  作者：Zhenwen Fu、Michael D. Morse

  DOI：10.1063/1.455850

  日期：1989.4

  Diatomic nickel–copper, NiCu, has been investigated by resonant two-photon ionization spectroscopy in a jet-cooled molecular beam. Six band systems have been identified over the range 11 500–16 500 cm−1. The ground state of NiCu has been determined to be X 2Δ5/2, with ω″e =273.01±1.15 cm−1, ω″ex″e =1.00±0.38 cm−1, and r″e =2.233±0.006 Å. This state derives from a strongly bound (2.05±0.10 eV) 3d10Cu3d9Ni 4sσ2 configuration. Excited states observed in this work derive from the more weakly bound 3d10Cu3d8Ni 4sσ24sσ*1 configuration, and are characterized by smaller vibrational frequencies (191–208 cm−1) and a longer bond length (2.351±0.005 Å) than the ground X 2Δ5/2 state.
• The bond energy of Ni+2
  作者：Li Lian、C.-X. Su、P.B. Armentrout

  DOI：10.1016/0009-2614(91)87135-x

  日期：1991.5

  The kinetic energy dependence of collision-induced dissociation (CID) of Ni2+ and Ni3+ with Xe has been investigated with a guided ion beam mass spectrometer. Interpretation of the CID cross section threshold of Ni2+ allows the binding energy of Ni2+ to be determined as 2.08 +/- 0.07 eV. This value is also confirmed by the CID cross section for Ni3+. This bond energy is well below the range of 3 to 3.5 eV obtained from the photodissociation of Ni2Ar+. The origins of the discrepancy between the two studies are discussed.
• Spectroscopic studies of nickel and iron clusters at 12 K
  作者：E. M. Nour、C. Alfaro‐Franco、K. A. Gingerich、J. Laane

  DOI：10.1063/1.452699

  日期：1987.5

  The electronic and far-infrared spectra of nickel and iron clusters trapped in argon matrices at 12 K are reported. The ν3 antisymmetric stretching frequencies for Ni3 and Fe3 were observed for the first time at 198 and 180 cm−1, respectively. The fr and frr force constants for Ni3 are calculated to be 0.80 and 0.13 mdyn/Å, respectively. For Fe3 these are 0.67 and 0.13 mdyn/Å.