1,4-双(二甲基膦)丁烷 | 200194-52-1

• 物质功能分类: 有机原料 - 有机膦化合物
• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 中文名称: 1,4-双(二甲基膦)丁烷
• 英文名称: 1,4-Bis(dimethylphosphino)butane
• 英文别名: 4-dimethylphosphanylbutyl(dimethyl)phosphane
• CAS: 200194-52-1
• 化学式: C₈H₂₀P₂
• mdl: MFCD01074555
• 分子量: 178.19
• InChiKey: FNAYAXPWEKXHQU-UHFFFAOYSA-N

物化性质

• 沸点：
  225.8±23.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• CARBONYLATION PROCESS
  申请人：Zoeller Joseph Robert

  公开号：US20090247783A1

  公开（公告）日：2009-10-01

  Disclosed is an improved carbonylation process for the production of carboxylic acids, carboxylic acid esters, and/or carboxylic acid anhydrides wherein a carbonylation feedstock compound selected from one or more organic oxygenates such as alcohols, ethers, and esters is contacted with carbon monoxide in the presence of a carbonylation catalyst and one or more onium compounds. The carbonylation process differs from known carbonylation processes in that a halide compound, other than the onium salt, such as a hydrogen halide (typically, hydrogen iodide) and/or an alkyl halide (typically, methyl iodide), extraneous or exogenous to the carbonylation process is not fed or supplied to the process. The process can be improved by using a bidentate ligand comprising two functional groups selected from tertiary amines and tertiary phosphines, such as 2,2′-bipyridine and diphosphine derivatives.

  本文披露了一种改进的羰基化过程，用于生产羧酸、羧酸酯和/或羧酸酐。在该过程中，选择一种或多种有机氧化物，如醇、醚和酯，作为羰基化原料化合物，并在羰基化催化剂和一种或多种离子化合物的存在下与一氧化碳接触。该羰基化过程与已知的羰基化过程不同之处在于，除了离子盐以外，不向过程中提供卤化物化合物，如氢卤化物（通常为氢碘酸）和/或烷基卤化物（通常为甲基碘化物）。该过程可以通过使用双齿配体来改进，该双齿配体包括两种从三级胺和三级膦中选择的功能基团，例如2,2'-联吡啶和二膦衍生物。
• Phosphorescent Osmium (II) complexes and uses thereof
  申请人：Tao Ye

  公开号：US20050137400A1

  公开（公告）日：2005-06-23

  There is disclosed herein phosphorescent compounds, uses thereof, and devices including organic light emitting diode (OLEDs) including such compounds. Compounds of interest include: wherein A is Os or Ru The anionic chelating chromophores Ncircumflex over ( )}N, which are formed by connecting one pentagonal ring structure containing at least two nitrogen atoms to a hexagonal pyridine type of fragment via a direct carbon-carbon linkage. L is a neutral donor ligand; the typical example includes carbonyl, pyridine, phosphine, arsine and isocyanide; two neutral L's can also combine to produce the so-called chelating ligand such as 2,2′-bipyridine, 1,10-phenanthroline and N-heterocyclic carbene (NHC) ligand, or bidentate phosphorous ligands such as 1,2-bis(diphenylphosphino)ethane, 1,2-bis(diphenylphosphino)benzene. L can occupy either cis or trans orientation. When L occupies the trans position, the preferred structure contains both the hexagonal fragment of NAN as well as its pentagonal fragment located at the trans position respect to their counterparts of the second NAN chromophore. When L occupies the cis position, the preferred structure consists of the pentagonal unit of Ncircumflex over ( )}N chromophores residing opposite to the L. X 1 , X 2 and X 3 independently are C or N; when X 2 is N, R, is omitted, when X 3 is N, R 2 is omitted, R 1 is H, C1-C8 alkyl, C1-C8 substituted phenyl or C1-C4 perfluoroalkyl, R 2 is H, F or cyano substituent, X 4 is either C or N; X 4 may locate at any position of the hexagonal ring, when X 4 is N and R 3 and R 4 are not linked to X 4 , R 3 is H, methyl or C1-C3 small alkyl, R 4 is H, methyl or C1-C3 small alkyl, or R 3 and R 4 together form an additional conjugated unit with structure

  本文介绍了荧光化合物及其用途，以及包括这些化合物的有机发光二极管（OLED）在内的装置。感兴趣的化合物包括：其中A是Os或Ru。阴离子螯合色团Ncircumflex over ( )}N是通过将至少含有两个氮原子的五边形环结构与一个六边形吡啶类型的片段通过直接碳-碳键连接而形成的。L是一个中性给体配体；典型的例子包括羰基、吡啶、膦、砷和异氰酸酯；两个中性的L也可以组合成所谓的螯合配体，如2,2′-联吡啶、1,10-邻菲啰啉和N-杂环卡宾（NHC）配体，或者是双齿膦配体，如1,2-双(二苯基膦基)乙烷、1,2-双(二苯基膦基)苯。L可以占据顺式或反式位向。当L占据反式位置时，首选结构包含NAN的六边形片段以及其位于反向位置的五边形片段，相对于第二个NAN色团的对应物。当L占据顺式位置时，首选结构由Ncircumflex over ( )}N色团的五边形单元组成，位于L的对面。X1、X2和X3独立地是C或N；当X2为N时，省略R；当X3为N时，省略R2；R1为H、C1-C8烷基、C1-C8取代苯基或C1-C4全氟烷基；R2为H、F或氰基取代基；X4为C或N；当X4为N且R3和R4未与X4连接时，X4可以位于六边形环的任何位置；R3为H、甲基或C1-C3小烷基；R4为H、甲基或C1-C3小烷基；或者R3和R4共同形成具有结构的额外共轭单元。
• METHYL-IODIDE-FREE CARBONYLATION OF AN ALCOHOL TO ITS HOMOLOGOUS ALDEHYDE AND/OR ALCOHOL
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：US20160185701A1

  公开（公告）日：2016-06-30

  Disclosed is a process for the reductive carbonylation of a low molecular weight alcohol to produce the homologous aldehyde and/or alcohol. The process includes conducting the reaction to produce the aldehyde in the presence of a catalyst complex composed of cobalt, an onium cation and iodide in a ratio of 1:2:4 with a phosphine ligand. A ruthenium co-catalyst is used in the production of the homologous alcohol. The reductive carbonylation reaction does not require an additional iodide promoter and produces a crude reductive carbonylation product substantially free of methyl iodide.

  本发明公开了一种还原羰基化低分子量醇以产生同系物醛和/或醇的过程。该过程包括在催化剂复合物的存在下进行反应，该催化剂复合物由钴、离子和碘组成，比例为1:2:4，含有膦配体，以产生醛。在同系物醇的生产中使用了钌共催化剂。还原羰基化反应不需要额外的碘促进剂，并且产生的粗还原羰基化产物基本上不含甲基碘。
• PROCESS FOR PRODUCTION OF AROMATIC AMIDE CARBOXYLIC ACID DERIVATIVE
  申请人：Kitajima Kazuki

  公开号：US20130317247A1

  公开（公告）日：2013-11-28

  The invention provides a method for producing an aromatic amide carboxylic acid derivative represented by the following Formula (2), including a step of reacting an aromatic amide halide derivative represented by the following Formula (1) with carbon monoxide. In the following Formulae (1) and (2), R 1 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; X 1 represents a fluorine atom or a cyano group; X 2 represents a halogen atom; and n represents an integer of from 0 to 3.

  该发明提供了一种制备下式（2）所表示的芳香族酰胺羧酸衍生物的方法，包括将下式（1）所表示的芳香族酰胺卤代衍生物与一氧化碳反应的步骤。在下式（1）和（2）中，R1表示氢原子或具有1至6个碳原子的烷基；X1表示氟原子或氰基；X2表示卤素原子；n表示0至3的整数。
• Process for production of monoalkyl ethers
  申请人：KAO CORPORATION

  公开号：US20010056212A1

  公开（公告）日：2001-12-27

  A process for producing a monoalkyl ether which comprises a first step of contacting the following components (A) and (B):(A): an aqueous liquid phase containing: (a 1 ) a C 3-6 polyol having 3 or 4 hydroxyl groups, a palladium compound, a water-soluble tertiary phosphine or phosphite, and water; or (a 2 ) a C 3-6 polyol having 3 to 4 hydroxyl groups, a complex of palladium and a water-soluble tertiary phosphine or phosphite, and water, and (B): an oily liquid phase containing a conjugated diene, to give an alkadienyl ether containing an alkadienyl group resulting from dimerization of conjugated dienes; and a second step of hydrogenating the alkadienyl group in the alkadienyl ether in a hydrogen atmosphere in the presence of a catalyst containing an element selected from the Groups 8 to 10 elements of the periodic table. According to the process of the invention, monoalkyl ethers of polyols are produced selectively in a simple manner and advantageously from the economical viewpoint. The present process enables recovery and recycling of the catalyst.

  一种制备单烷基醚的方法，包括以下步骤：第一步，将以下组分（A）和（B）接触：（A）含有以下成分的水相液体：（a1）具有3或4个羟基的C3-6多元醇，钯化合物，水溶性三级膦或亚磷酸酯和水；或（a2）具有3到4个羟基的C3-6多元醇，钯和水溶性三级膦或亚磷酸酯的复合物和水；（B）含有共轭二烯的油状液相，以产生含有由二聚共轭二烯产生的烯基二烯醚的烯基二烯基醚；第二步，在氢气氛中，在周期表8至10族元素中选择的元素的催化剂存在下，对烯基二烯基醚中的烯基二烯基进行氢化。根据本发明的方法，可以简单地选择性地制备多元醇的单烷基醚，并从经济角度获得优势。本方法可以使催化剂得到回收和再利用。