platinum chromium (PtCr)-based everolimus-eluting | 160110-59-8

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: platinum chromium (PtCr)-based everolimus-eluting
• 英文别名: platinum chromium everolimus-eluting PE；platinum-chromium everolimus-eluting；Platinum Chromium；chromium platinum；Chromium--platinum (1/1)；chromium;platinum
• CAS: 160110-59-8
• 化学式: CrPt
• 分子量: 247.076
• InChiKey: MMAADVOQRITKKL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  [chloropentaammineplatinum(IV)][trioxalatochromate(III)]*4H2O 在 H₂ 作用下， 以 neat (no solvent) 为溶剂， 生成 platinum chromium (PtCr)-based everolimus-eluting
  参考文献：
  名称：

  Double complex salts [Pt(NH3)5Cl][M(C2O4)3] · nH2O (M = Fe, Co, Cr): Synthesis and study

  摘要：

  Double complexes [Pt(NH3)(5)Cl][Fe(C2O4)(3)] center dot 4H(2)O, [Pt(NH3)(5)Cl][Co(C2O4)(3)] center dot 2H(2)O, and [Pt(NH3)(5)Cl][Cr(C2O4)(3)] center dot 4H(2)O were synthesized and studied by single-crystal X-ray diffraction, X-ray phase analysis, differential thermal analysis, elemental analysis, and IR spectroscopy. The crystal structures of the compounds were examined from the viewpoint of the close packing of coordination polyhedra. The thermal properties of the synthesized complexes and K-3[M(C2O4)(3)] salts (M = Fe, Co, Cr) were compared. A procedure for the synthesis of the FePt, CoPt, and CrPt intermetallic compounds through the thermolysis of the obtained complexes was developed.

  DOI：

  10.1134/s0036023607100014

文献信息

• Double complex salts [M(NH3)5Cl][M′Br4] (M = Rh, Ir, Co, Cr, Ru; M′ = Pt, Pd): Synthesis, x-ray diffraction characterization, and thermal properties
  作者：Yu. V. Shubin、A. V. Zadesenets、A. B. Venediktov、S. V. Korenev

  DOI：10.1134/s0036023606020070

  日期：2006.2

  Double complex salts (DCSs) with [M(NH3)(5)Cl](2+) (M = Rh, Ir, Co, Cr, Ru) cations and [PtBr4](2-) anions were prepared in high yields. The salts were two-phase mixtures of the anhydrous and monohydro DCSs. Anhydrous analogues containing [PdBr4](2-) anions with M = Cr or Ru were synthesized. All the compounds were characterized using a set of physicochemical methods. The crystal structure of chloropentaamminechromium(III) tetrabromopalladate(II) was solved: space group Pnma, Z = 4, a = 17.068(2) angstrom, b = 8.315(12) angstrom, c = 9.653(14) angstrom. The [M(NH3)(5)Cl][M'X-4] (M = Rh, Ir, Co, Cr, Ru; M' = Pd, Pt; X = Cl, Br) compounds were shown to be isostructural. The [M(NH3)(5)Cl][PtBr4] center dot H2O monohydrates are isostructural to the [M(NH3)(5)Cl][PdCl4] center dot H2O monohydrates (space group P2(1)/c, z = 4). The properties of the compounds were comparatively analyzed. The tendencies of the thermal stability of the complexes were elucidated. The thermolysis products of the double complex salts obtained under a helium or hydrogen atmosphere were studied.
• Plusnin; Shubin; Yusenko, Russian Journal of Inorganic Chemistry, 2004, vol. 49, # 8, p. 1148 - 1153
  作者：Plusnin、Shubin、Yusenko、Baidina、Korda、Korenev

  DOI：——

  日期：——
• Double complex salts [Pt(NH3)5Cl][M(C2O4)3] · nH2O (M = Fe, Co, Cr): Synthesis and study
  作者：K. V. Yusenko、D. B. Vasil’chenko、A. V. Zadesenets、I. A. Baidina、Yu. V. Shubin、S. V. Korenev

  DOI：10.1134/s0036023607100014

  日期：2007.10

  Double complexes [Pt(NH3)(5)Cl][Fe(C2O4)(3)] center dot 4H(2)O, [Pt(NH3)(5)Cl][Co(C2O4)(3)] center dot 2H(2)O, and [Pt(NH3)(5)Cl][Cr(C2O4)(3)] center dot 4H(2)O were synthesized and studied by single-crystal X-ray diffraction, X-ray phase analysis, differential thermal analysis, elemental analysis, and IR spectroscopy. The crystal structures of the compounds were examined from the viewpoint of the close packing of coordination polyhedra. The thermal properties of the synthesized complexes and K-3[M(C2O4)(3)] salts (M = Fe, Co, Cr) were compared. A procedure for the synthesis of the FePt, CoPt, and CrPt intermetallic compounds through the thermolysis of the obtained complexes was developed.