3-methyl-N-(3-triethoxysilylpropyl)-3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dien-1-yl)butanamide | 1224732-66-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 3-methyl-N-(3-triethoxysilylpropyl)-3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dien-1-yl)butanamide
• CAS: 1224732-66-4
• 化学式: C₂₃H₃₉NO₆Si
• 分子量: 453.651
• InChiKey: FRBUYTBTMVHPDE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.76
• 重原子数：
  31
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  90.9
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3-氨基丙基三乙氧基硅烷 、 succinimidyl β,β,2,4,5-pentamethyl-3,6-dioxo-1,4-cyclohexadiene-1-propanoate 以 二氯甲烷 为溶剂， 以75%的产率得到3-methyl-N-(3-triethoxysilylpropyl)-3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dien-1-yl)butanamide
  参考文献：
  名称：

  Bifunctional Patterning of Mixed Monolayer Surfaces Using Scanning Probe Lithography for Multiplexed Directed Assembly

  摘要：

  The patterning of a surface with more than one type of functionality in spatially resolved fashion is described. A scanning probe was used to create patterns composed of two orthogonal types of functionality within a dense, electrochemically active mixed monolayer via a simple modulation of the applied surface bias. One reductive pathway produces surface-bound amine moieties while the other creates an oxidized surface. The two newly created surface functionalities can each be used independently to locally deposit complementary materials such as electron- or hole-transporting molecules via self-assembly.

  DOI：

  10.1021/ja101627e