N-hexylperylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide | 1190425-64-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N-hexylperylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide
• CAS: 1190425-64-9
• 化学式: C₅₉H₆₁BrN₂O₄
• 分子量: 942.048
• InChiKey: BOZXIMBGWRFHHY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.24
• 重原子数：
  66.0
• 可旋转键数：
  20.0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  74.76
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  2-{5'-[7-(5'-tributylstannyl-2,2'-bithien-5-yl)-9,9-dioctylfluoren-2-yl]-2,2'-bithien-5-yl}-9,9-dioctylfluorene 、 N-hexylperylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide 在 四(三苯基膦)钯 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 24.0h， 以58%的产率得到F3T4-hP
  参考文献：
  名称：

  Monodisperse Co-oligomer Approach toward Nanostructured Films with Alternating Donor−Acceptor Lamellae

  摘要：

  A series of donor-acceptor (D-A) co-oligomers with oligo(fluorene-alt-bithiophene) and perylene diimide as donor and acceptor segments, respectively, have been designed and synthesized. They can self-assembly into alternating D-A lamellar nanostructured films with the periods depending on the molecular length. These films have been successfully used in fabrication of high-performance single-molecular solar cells with power conversion efficiency up to 1.50%.

  DOI：

  10.1021/ja905980w
• 作为产物：
  描述：

  7-bromo-9,9-dioctyl-9H-fluoren-2-amine 、 perylene-3,4-anhydride-9,10-hexylimide 在 咪唑 、 zinc diacetate 作用下， 反应 4.0h， 以75%的产率得到N-hexylperylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide
  参考文献：
  名称：

  Monodisperse Co-oligomer Approach toward Nanostructured Films with Alternating Donor−Acceptor Lamellae

  摘要：

  A series of donor-acceptor (D-A) co-oligomers with oligo(fluorene-alt-bithiophene) and perylene diimide as donor and acceptor segments, respectively, have been designed and synthesized. They can self-assembly into alternating D-A lamellar nanostructured films with the periods depending on the molecular length. These films have been successfully used in fabrication of high-performance single-molecular solar cells with power conversion efficiency up to 1.50%.

  DOI：

  10.1021/ja905980w