2,3,5,6-tetrakis-(morpholinomethyl)hydroquinone | 6452-82-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2,3,5,6-tetrakis-(morpholinomethyl)hydroquinone
• 英文别名: 2,3,5,6-tetrakis-morpholin-4-ylmethyl-benzene-1,4-diol；Tetrakis-(morpholinomethyl)-hydrochinon；Tetrakis(morpholinomethyl)hydrochinon；2,3,5,6-Tetrakis(morpholin-4-ylmethyl)benzene-1,4-diol
• CAS: 6452-82-0
• 化学式: C₂₆H₄₂N₄O₆
• 分子量: 506.643
• InChiKey: IGVCZVYEUKFKOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.9
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  90.3
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  2,3,5,6-tetrakis-(morpholinomethyl)hydroquinone 在 氢溴酸 、 溶剂黄146 作用下， 生成 1,4-Bis(acetoxy)-2,3,5,6-tetrakis(bromomethyl)benzol
  参考文献：
  名称：

  Preparation of Acetoxybenzyl Bromides

  摘要：

  DOI：

  10.1021/jo01032a040
• 作为产物：
  描述：

  吗啉 、 聚合甲醛 、 对苯二酚 以 1,4-二氧六环 为溶剂， 反应 26.0h， 生成 2,3,5,6-tetrakis-(morpholinomethyl)hydroquinone
  参考文献：
  名称：

  Novel synthesis of silver nanoparticles using 2,3,5,6-tetrakis-(morpholinomethyl) hydroquinone as reducing agent

  摘要：

  2,3,5,6-Tetrakis-(morpholinomethyl) hydroquinone (TMMH) was used as a reducing agent to synthesize spherical shaped silver nanoparticles in water-ethanol medium without using any stabilizing and capping agents. The reducing agent TMMH is prepared by Mannich-type reaction method and H-1 NMR, C-13 NMR and FT-IR spectroscopy techniques were used to characterize the compound (TMMH). The nature of bonding, structural and optical properties of the final product were analyzed using different techniques such as UV-Vis spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR). The interaction between silver and reducing agent was confirmed by using FTIR analysis. The final product obtained showed higher crystallinity with cubic structure and an average crystalline size of about 20 nm. The results revealed that it is possible to synthesize crystalline Ag nanoparticles using organic compound as reducing agent. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2012.03.081

文献信息

• AG LOADED SILICA NANOPARTICLE/NANOGEL FORMULATION, METHODS OF MAKING, AND METHODS OF USE
  申请人：Santra Swadeshmukul

  公开号：US20130108678A1

  公开（公告）日：2013-05-02

  Embodiments of the present disclosure, in one aspect, relate to compositions including a silver/silica nanocomposite, methods of making a silver/silica nanocomposite, methods of using a silver/silica nanocomposite, and the like.
• US9491946B2
  申请人：——

  公开号：US9491946B2

  公开（公告）日：2016-11-15
• Preparation of Acetoxybenzyl Bromides
  作者：D. L. Fields、J. B. Miller、D. D. Reynolds

  DOI：10.1021/jo01032a040

  日期：1964.9
• Novel synthesis of silver nanoparticles using 2,3,5,6-tetrakis-(morpholinomethyl) hydroquinone as reducing agent
  作者：P. Manivel、A. Balamurugan、N. Ponpandian、D. Mangalaraj、C. Viswanathan

  DOI：10.1016/j.saa.2012.03.081

  日期：2012.9

  2,3,5,6-Tetrakis-(morpholinomethyl) hydroquinone (TMMH) was used as a reducing agent to synthesize spherical shaped silver nanoparticles in water-ethanol medium without using any stabilizing and capping agents. The reducing agent TMMH is prepared by Mannich-type reaction method and H-1 NMR, C-13 NMR and FT-IR spectroscopy techniques were used to characterize the compound (TMMH). The nature of bonding, structural and optical properties of the final product were analyzed using different techniques such as UV-Vis spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR). The interaction between silver and reducing agent was confirmed by using FTIR analysis. The final product obtained showed higher crystallinity with cubic structure and an average crystalline size of about 20 nm. The results revealed that it is possible to synthesize crystalline Ag nanoparticles using organic compound as reducing agent. (C) 2012 Elsevier B.V. All rights reserved.