[1-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononyl)vinyl]benzene | 82486-03-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [1-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononyl)vinyl]benzene
• 英文别名: 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoroundec-1-en-2-ylbenzene
• CAS: 82486-03-1
• 化学式: C₁₇H₉F₁₇
• 分子量: 536.231
• InChiKey: AYHIJDKEGCMFND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  34
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为产物：
  描述：

  全氟辛基碘烷 、 三丁基(2-苯基丙-2-烯基)锡烷 在 偶氮二异丁腈 作用下， 以 正己烷 为溶剂， 反应 5.0h， 以93%的产率得到[1-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononyl)vinyl]benzene
  参考文献：
  名称：

  Reverse Fluorous Solid-Phase Extraction:  A New Technique for Rapid Separation of Fluorous Compounds

  摘要：

  Fluorous-tagged compounds can rapidly be separated from organic (non-tagged) compounds by the new separation technique of reverse fluorous solid-phase extraction (r-fspe). In a reversal of the roles of solid and liquid phases in standard fluorous spe, a mixture is charged to a polar solid phase (standard silica gel) and then eluted with a fluorous solvent or solvent mixture. The organic components of the mixture are retained, while the fluorous components pass.

  DOI：

  10.1021/ol049040o

文献信息

• Separation of fluorous compounds
  申请人：Curran P. Dennis

  公开号：US20050283032A1

  公开（公告）日：2005-12-22

  A method of separating at least a first non-fluorous compound from a mixture of compounds including at least the first non-fluorous compound and a second fluorous compound includes: charging the of compounds to a non-fluorous solid (stationary) phase and eluting with a fluorous eluting fluid (mobile phase). In one embodiment, the non-fluorous solid phase is polar in nature. The method can further include a second phase elution with a suitable organic solvent. A method conducting a chemical reaction, includes: mixing at least a first fluorous compound and a second compound, the first fluorous compound differing in fluorous nature from the second compound; exposing the first mixture to conditions to convert at least one of the first fluorous compound and the second compound to give a second mixture containing at least a third compound, charging the second mixture to a non-fluorous solid phase; and eluting with a fluorous fluid

  将至少一个非氟化合物从包括至少第一个非氟化合物和第二个氟化合物的混合物中分离出来的方法包括：将化合物充电到非氟固体（静态）相，并用氟溶剂流体（移动相）洗脱。在一个实施例中，非氟固相具有极性特性。该方法还可以包括使用适当的有机溶剂进行第二相洗脱。一种进行化学反应的方法包括：混合至少一个第一氟化合物和第二化合物，第一个氟化合物在氟性质上与第二化合物不同；将第一混合物暴露在条件下，将至少一个第一个氟化合物和第二化合物转化为至少包含第三化合物的第二混合物，将第二混合物充电到非氟固相；并用氟溶剂洗脱。
• The Different Faces of Photoredox Catalysts: Visible-Light-Mediated Atom Transfer Radical Addition (ATRA) Reactions of Perfluoroalkyl Iodides with Styrenes and Phenylacetylenes
  作者：Thomas Rawner、Eugen Lutsker、Christian A. Kaiser、Oliver Reiser

  DOI：10.1021/acscatal.8b00847

  日期：2018.5.4

  phenylacetylenes using readily available copper phenanthroline catalyst is reported. In contrast to commonly employed [Ru(bpy)3]Cl2, [Ru(phen)3]Cl2 or fac-Ir(ppy)3, [Cu(dap)2]Cl is capable to convert styrenes to the corresponding perfluoroalkyl tagged ethylbenzenes, pointing toward an additional role of the copper catalyst beyond photoinduced electron transfer. An inner sphere catalytic cycle involving Cu(III)

  据报道，使用现成的菲咯啉铜催化剂进行光氧化还原催化的苯乙烯和苯乙炔的碘全氟烷基化反应。与常用的[Ru（bpy）3 ] Cl 2，[Ru（phen）3 ] Cl 2或fac -Ir（ppy）3相比，[Cu（dap）2 ] Cl能够将苯乙烯转化为相应的全氟烷基标记的乙苯，除了光诱导的电子转移外，还指出了铜催化剂的其他作用。提出了一种涉及Cu（III）中间体或[CuI] +中间体的配体抽象的内球催化循环。
• SEPARATION OF FLUOROUS COMPOUNDS
  申请人：CURRAN DENNIS P.

  公开号：US20080194887A1

  公开（公告）日：2008-08-14

  A method of separating at least a first non-fluorous compound from a mixture of compounds including at least the first non-fluorous compound and a second fluorous compound includes: charging the of compounds to a non-fluorous solid (stationary) phase and eluting with a fluorous eluting fluid (mobile phase). In one embodiment, the non-fluorous solid phase is polar in nature. The method can further include a second phase elution with a suitable organic solvent. A method conducting a chemical reaction, includes: mixing at least a first fluorous compound and a second compound, the first fluorous compound differing in fluorous nature from the second compound; exposing the first mixture to conditions to convert at least one of the first fluorous compound and the second compound to give a second mixture containing at least a third compound, charging the second mixture to a non-fluorous solid phase; and eluting with a fluorous fluid

  一种从包含至少第一个非氟化合物和第二个氟化合物的混合物中分离至少第一个非氟化合物的方法包括：将化合物充电到非氟性固体（静态）相，并用氟性洗脱流体（移动相）洗脱。在一个实施例中，非氟性固相具有极性。该方法还可以包括使用适当的有机溶剂进行第二相洗脱。一种进行化学反应的方法包括：混合至少第一个氟化合物和第二个化合物，第一个氟化合物在氟性质上与第二个化合物不同；将第一混合物暴露于条件下，以转化至少第一个氟化合物和第二个化合物中的一个，以给出包含至少第三个化合物的第二混合物，将第二混合物充电到非氟性固体相中；并用氟性流体洗脱。
• Reactions of RfI(Ph)OSO2CF3 with alkenes and alkadienes
  作者：Teruo Umeoto、Yuriko Kuriu、Shin-ichi Nakayama

  DOI：10.1016/s0040-4039(00)87051-3

  日期：1982.1
• UMEMOTO, TERUO;KURIU, YURIKO;NAKAYAMA, SHIN-ICHI, TETRAHEDRON LETT., 1982, 23, N 11, 1169-1172
  作者：UMEMOTO, TERUO、KURIU, YURIKO、NAKAYAMA, SHIN-ICHI

  DOI：——

  日期：——