RADICAL-GENERATING CATALYST, RADICAL PRODUCTION METHOD, OXIDATION REACTION PRODUCT PRODUCTION METHOD, CHEMICAL AGENT, AND CHEMICAL AGENT FOR AGRICULTURE AND LIVESTOCK
申请人:Acenet Inc.
公开号:EP3626339A1
公开(公告)日:2020-03-25
The present invention is intended to provide a radical generating catalyst that can generate (produce) radicals under mild conditions. In order to achieve the above object, the first radical generating catalyst of the present invention includes: at least one selected from the group consisting of amino acids, peptides, phospholipids, and salts thereof. The second or third radical generating catalyst of the present invention includes an ammonium salt represented by the following chemical formula (XI) (excluding peroxodisulfate) and having a Lewis acidity of 0.4 eV or more.
In the chemical formula (XI), R11, R21, R31, and R41 are each a hydrogen atom or an aromatic ring, or an alkyl group, the alkyl group may include an ether bond, a carbonyl group, an ester bond, or an amide bond, or an aromatic ring, and R11, R21, R31, and R41 may be identical to or different from each other; or two or more of R11, R21, R31, and R41 may be integrated to form a ring structure with N+ to which they are bonded, and the ring structure may be saturated or unsaturated, aromatic or non-aromatic, and may or may not have one or more substituents. X- is an anion (excluding peroxodisulfate ion).
本发明旨在提供一种能在温和条件下生成(产生)自由基的自由基生成催化剂。为了实现上述目的,本发明的第一种自由基生成催化剂包括:至少一种选自氨基酸、肽、磷脂及其盐组成的组。本发明的第二或第三自由基生成催化剂包括由以下化学式(XI)代表的铵盐(不包括过二硫酸盐),其路易斯酸度为 0.4 eV 或以上。
在化学式(XI)中,R11、R21、R31 和 R41 各为氢原子或芳香环,或烷基,烷基可包括醚键、羰基、酯键或酰胺键,或芳香环,R11、R21、R31 和 R41 可彼此相同或不同;或两个或两个以上的 R11、R21、R31 和 R41 可与它们所键合的 N+ 整合形成环结构,该环结构可以是饱和或不饱和的,芳香或非芳香的,可以有或没有一个或多个取代基。X- 是阴离子(不包括过二硫酸根离子)。